Chemical and Natural Gas Engineering

Faculty & Staff

Dr. Horacio A. Duarte


Associate Professor

 

Education 

1988

Ph.D.

Texas A&M University, College Station , Chemical Engineering

Dissertation: A High Pressure Isochoric Apparatus to Determine Accurate pVT and Phase Equilibria on Fluids: Application to Carbon-Dioxide/Nitrogen

1980

M. Eng.

Instituto Tecnológico de Monterrey, México ,Chemical Engineering

1977

B.S.

Instituto Tecnológico de Durango, México, Chemical Engineering

 

 

 

Professional Experience

Jan. 2006-present

Associate Professor,Texas A&M University Kingsville,  Kingsville, TX

Granted Tenure May 2010

Feb. 2001-Dec. 2005

Thermodynamics Specialist, The Dow Chemical Company ,  South Charleston, WV

·       Responsible for measurement and correlation of physical properties

·       Developed a technique to measure the solubility and diffusion coefficient of gases in polymers using a magnetic suspension balance.

June 1999-Feb. 2001

Staff Engineer, Union Carbide Corporation , South Charleston, WV

Thermophysical Properties Skill Center, South Charleston Technical Center

May 1998- May 1999

Associate Professor, Texas A&M University - Kingsville ,Kingsville, TX

Chemical Engineering

Jan. 1994-May 1998

Assistant Professor, Texas A&M University - Kingsville ,Kingsville, TX

Chemical Engineering

1991-1993

Engineering Research Associate, Texas A&M University ,College Station, TX

Chemical Engineering Department

1989-1990

Research Associate, Texas Transportation Institute,College Station, TX

1988-1989

Engineering Research Associate, Texas A&M University , College Station, TX

Chemical Engineering Department    

1982-1988

Research Assistant, Texas A&M University , College Station, TX

Chemical Engineering Department    

1980-1981

Assistant Professor, Instituto Tecnológico de Durango  ,Durango, México

1979

Instructor, Instituto Tecnológico de Monterrey, Monterrey, México

 

 

CONSULTING AND SUMMER RESEARCH

 

Guest Researcher

DOD Summer Research Fellowship May-July 2022, Army DEVCOM Laboratory, Rice University

Sabbatical Leave

Thermodynamics Center (Ruhr University) August-December 2021, Bochum, Germany

Consultant

MATRIC (Mid Atlantic Technology Research and Innovation Center) – 2012, 2010, and 2008, South Charleston, WV

Expert Witness

Law Firm of Abboud and Ware – 1999, Dallas, TX

Guest Researcher

Thermophysics Division, NIST (National Institute of Standards and Technology) – 2009, Boulder, CO

Guest Researcher

Office of Naval Research – 2008, Indian Head, MD

Visiting Associate Professor

Texas A&M University – 2006, College Station, TX

Guest Researcher

Thermophysics Division, NIST (National Institute of Standards and Technology) – 1998, 1997, and 1995, Boulder, CO

Guest Researcher

Department of Chemical Engineering, Texas A&M University – 1996 and 1994, College Station, TX

 

AWARDS AND HONORS

    2008

Chancellor’s Teaching Excellence Award, Texas A&M University System

    2004

Team Work Award for Excellence in Science, Core R&D – The Dow Chemical Company

 

COURSES TAUGHT

  • Chemical Process Design I, II and III courses 
  • Material and Energy Balances course
  • Chemical Engineering Thermodynamics (the graduate and undergraduate courses) 
  • Biochemical Engineering course
  • Process Dynamics and Control (graduate and undergraduate courses)
  • Separation processes (graduate and undergraduate courses)  

 

RESEARCH SUMMARY 

Dr. Duarte has more than 25 years research experience in Thermodynamics.  He has measured PVT and heat capacity of new alternative refrigerants. During his tenure at Union Carbide Corporation/Dow Chemical, he measured a wide variety of physical properties of industrially important chemicals (measurements of VLE, LLE, SLE, solubility of gases in liquids, solubility of gases in polymers, and diffusion coefficient of gases in polymers). He developed a technique to measure the solubility and diffusion coefficient of gases and vapors in polymers using a magnetic suspension balance. As a professor, he has directed more than 40 master’s research projects at Texas A&M University – Kingsville.

 

PUBLICATIONS

 

Refereed papers:

 

Eisenbach, T.,Duarte, H.A., Wedler,C., Pflieger,C., Muhler, M., Span, R., Experimental Investigations on the Adsorptive Behavior of H2O Vapor on HTC Char Particles., Applied Energy and Advances in Applied Energy, submitted, December, 2022.

 

Ramirez-Beltran, N., Rodriguez, H., Estebez, A. and Duarte, H.A., A Neural Network Approach to Predict Activity Coefficients, The Canadian Journal of Chemical Engineering, 87,  748-760, 2009.

 

Duarte-Garza H.A. and Magee J.W., Isochoric P-ρ-T Measurements on {(x)CO2 + (1-x) C2H6, x ≅ 0.25, 0.49, 0.74} from (200 to 400) K at Pressures to 35 Mpa, Journal of Chemical and Engineering Data, 46, 1095-1100, 2001.

 

Duarte-Garza H.A. and Magee J.W., Molar Heat Capacity at Constant  Volume of Trifluoromethane (R23) from the Triple-Point Temperature to 342 K at Pressures to 33 Mpa, , International Journal of Thermophysics, Vol 21, No. 6, 1351-1372, 2000.

 

Duarte-Garza H.A. and Magee J.W., Isochoric P-ρ-T and Heat Capacity Cv Measurements on {xC3H8 + (1-x)I-C4H10, x ≈ 0.7, 0.3} from 200 to 400 K at Pressures to 35 Mpa, Journal of Chemical and Engineering Data, 44, 1048-1054, 1999.

 

Duarte-Garza H.A. and Magee J.W., Subatmospheric Vapor Pressures  for Fluoromethane (R41), 1,1-Difluoroethane (R152a), and 1,1,1-Trifluoroethane (R143a) Evaluated from Internal Energy Measurements, International Journal of Thermophysics, Vol 20, No. 5, 1467-1481, 1999.

 

Duarte-Garza H.A., Holste J.C.,  Hall K.R., and Iglesias-Silva G.A., A Technique for Preparing Thermodynamic Property Tables Using Incomplete Data Sets, Fluid Phase Equilibria, 146, 123-137, 1998.

 

Sadeq J., Duarte H.A., and Serth R., Anomalous Results from Process Simulators, Chemical Engineering Education, 46-51, Winter 1997.

 

Duarte-Garza H.A. and Magee J.W., Subatmospheric Vapor Pressures Evaluated from Internal Energy Measurements, International Journal of Thermophysics, Vol 18, No. 1, 173-193, 1997.

 

Duarte-Garza H.A., Hwang C.A., Kellerman S., Miller R.C., Hall R.H., Holste J.C, Marsh, K.R., and Gammon B.E., Vapor Pressure, Vapor Density, and Liquid Density for 1,1-Dichlorofluoroethane (R141b), Journal of Chemical and Engineering Data, 42, 497-501, 1997.

 

Duarte-Garza H.A., Stouffer C.E., Hall, K.R., Holste J.C., Marsh K.N. and Gammon B.E., Experimental Critical Constants, Vapor Pressures, and Vapor  and Liquid Densities for Pentafluoroethane (R125), Journal of Chemical and Engineering Data, 42, 745-753, 1997.

 

Lau W.R., Hwang C.-A., Brugge H.B., Iglesias-Silva G.A., Duarte-Garza H.A., Rogers W.J., Gammon B.E., Marsh K.N., Hall K.R., and Holste J.C., A Continuously Weighed Pycnometer for Measuring Fluid Properties,  Journal of Chemical and Engineering Data, 42, 738-744, 1997.

 

Duarte-Garza H.A., Holste J.C., Hall K.R., Marsh K.N., and Gammon B.E., Isochoric PVT and Phase Equilibrium Measurements for Carbon Dioxide + Nitrogen, Journal of Chemical and Engineering Data, Vol 40, No. 3, 704-711, 1995.

 

Duarte-Garza H.A. et. al., Thermodynamic Properties of Pentafluoroethane (R125) and 1,1-Dichlorofluoroethane (R141b), ASHRAE paper DE-93-6-3, ASHRAE Trans., Vol 99, part 2, 1993.

 

Eubank P.T., Barrufet M.A., Duarte-Garza H.A. and Yurttas L., PVT Experiments for Precise VLE Data for Mixtures of Similar Volatility, Fluid Phase Equilibria, 52, 219-227, 1989.

 

Refereed reports:

 

Hwang C.H., Duarte-Garza H.A., Holste J.C., Eubank P.T.,and Hall K.R., Thermodynamic Properties of CO2 + CH4 Mixtures, A joint report by the Gas Processors Association and the Gas Research Institute, RR 138, 1995.

 

Duarte-Garza H.A., Holste J.C., Eubank P.T.,and Hall K.R, Thermodynamic Properties of CO2 + C2H6 Mixtures, A joint report by the Gas Processors Association and the Gas Research Institute, RR 139, 1995.

 

Duarte-Garza H.A., Holste J.C., Eubank P.T.,and Hall K.R, Thermodynamic Properties of CO2 + N2 Mixtures, A joint report by the Gas Processors Association and the Gas Research Institute, RR 140, 1995.

 

Non-refereed papers:

 

Eisenbach, T.,Duarte, H.A., Wedler,C., Pflieger,C., Muhler, M., Span, R., Experimental Investigations on the Adsorptive Behavior of H2O Vapor on HTC Char Particles., 14th International Conference on Applied Energy –ICAE2022, Aug 8-11, 2022, Bochum, Germany.

 

Duarte, H.A., Pullalarevu, G.R., Desai, D. and Nukala, N.K., Experimental Densities and Excess Volumes for the Binary Mixtures Benzene-Toluene, Acetone-Benzene and Acetone-Toluene at Various Temperatures and Atmospheric Pressure, AIChE Spring National Conference, Tampa, FL (April 27, 2009).

 

Duarte-Garza H.A., Ran Q., Marsh K.N., and Holste J.C., Enthalpies of Vaporization for Refrigerant AZ-20 (HFC-125/HFC32) from PVT Measurements, presented at the 13th Symposium on Thermophysical Properties, Boulder, CO, June 22-27 1997.

 

Duarte-Garza H.A. and Magee J.W. , Subatmospheric Vapor Pressures Evaluated from Internal Energy Measurements, presented at the 13th Symposium on Thermophysical Properties, Boulder, CO, June 22-27 1997.

 

Duarte-Garza H.A., Holste J.C. and Hall K.R., A Corrector Function for an Extended Corresponding States Model, presented at the 12th Symposium on Thermophysical Properties, Boulder, CO, June 19-24 1994.

 

Holste J.C., Duarte-Garza H.A., and Villamanan M.A., Thermodynamic Properties Measurements, Paper 93-WA/HT-60, presented at the ASME Winter Annual Meeting, New Orleans, Louisiana, December 1993.

 

Union Carbide Corporation and Dow Chemical project reports:  47 project reports.

 

 

 

 

Dr. Horacio A. Duarte